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CHEM 518

Photochemistry and Photophysics

This graduate-level course is about what molecules actually do once they absorb a photon — how an excited state forms, how long it survives, and which radiative, radiationless, or chemical pathway wins out before the molecule returns to the ground state. You'll work through the Jablonski diagram and selection rules in detail, apply them to canonical systems ranging from small organics like benzophenone and naphthalene to coordination complexes such as [Ru(bpy)3]2+, and consolidate the framework through two midterms, five problem sets, and a final. Building on undergraduate physical and inorganic chemistry, it gives you the vocabulary needed to read modern work on sensitizers, luminescent probes, solar energy conversion, and light-driven molecular machines.

Credit3ECTS5FacultyFaculty of ScienceBölümChemistry

Değerlendirme 100% — 3 adım

50%
30%
20%
Midterm Midterms 50%
Final Final Exam 30%
Homework Homework and projects 20%

Önerilen kaynaklar 1 kitap

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Önerilen
Photochemistry and Photophysics - Concepts
Research, Applications
Vincenzo Balzani · Paola Ceroni

Haftalık müfredat 14 hafta

Hafta 1
Introduction to Photochemistry and Photophysics - History, nature of light, absorption process
Hafta 2
Elementary Molecular Orbital Theory - General concepts; from H2 to metal complexes
Hafta 3
Light Absorption and Nature of the Excited State - Light Absorption - Selection Rules - Symmetry Selection Rules - Spin Selection Rules - The Franck–Condon Principle - Jablonski Diagram - Excited-State Deactivation - Vibrational Relaxation - Radiationless Deactivation - Radiative Deactivation - Radiative Lifetime - Chemical Reactions - Excited States: Physical and Chemical Properties: Lifetime, Energy, Geometry, Small Molecules - Selected Molecules: Oxygen, Naphthalene, Benzophenone, Zinc(II) Tetraphenyl Porphyrin, [Cr(en)3]3+, [Co(NH3)6]3+, [Ru(bpy)3]2+, Semiconductors
Hafta 4
Light Absorption and Nature of the Excited State - Light Absorption - Selection Rules - Symmetry Selection Rules - Spin Selection Rules - The Franck–Condon Principle - Jablonski Diagram - Excited-State Deactivation - Vibrational Relaxation - Radiationless Deactivation - Radiative Deactivation - Radiative Lifetime - Chemical Reactions - Excited States: Physical and Chemical Properties: Lifetime, Energy, Geometry, Small Molecules - Selected Molecules: Oxygen, Naphthalene, Benzophenone, Zinc(II) Tetraphenyl Porphyrin, [Cr(en)3]3+, [Co(NH3)6]3+, [Ru(bpy)3]2+, Semiconductors
Hafta 5
Light Absorption and Nature of the Excited State - Light Absorption - Selection Rules - Symmetry Selection Rules - Spin Selection Rules - The Franck–Condon Principle - Jablonski Diagram - Excited-State Deactivation - Vibrational Relaxation - Radiationless Deactivation - Radiative Deactivation - Radiative Lifetime - Chemical Reactions - Excited States: Physical and Chemical Properties: Lifetime, Energy, Geometry, Small Molecules - Selected Molecules: Oxygen, Naphthalene, Benzophenone, Zinc(II) Tetraphenyl Porphyrin, [Cr(en)3]3+, [Co(NH3)6]3+, [Ru(bpy)3]2+, Semiconductors
Hafta 6
Light Absorption and Nature of the Excited State - Light Absorption - Selection Rules - Symmetry Selection Rules - Spin Selection Rules - The Franck–Condon Principle - Jablonski Diagram - Excited-State Deactivation - Vibrational Relaxation - Radiationless Deactivation - Radiative Deactivation - Radiative Lifetime - Chemical Reactions - Excited States: Physical and Chemical Properties: Lifetime, Energy, Geometry, Small Molecules - Selected Molecules: Oxygen, Naphthalene, Benzophenone, Zinc(II) Tetraphenyl Porphyrin, [Cr(en)3]3+, [Co(NH3)6]3+, [Ru(bpy)3]2+, Semiconductors
Hafta 7
Molecular Organic Photochemistry - Basic Concepts - Carbonyl Compounds - Photochemistry of Other Organic Compounds - Nitrogen Compounds
Hafta 8
Molecular Organic Photochemistry - Basic Concepts - Carbonyl Compounds - Photochemistry of Other Organic Compounds - Nitrogen Compounds
Hafta 9
Photochemistry and Photophysics of Metal Complexes - Photophysical Properties - Relationships between Electrochemistry and Photochemistry - Cobalt (III) Complexes - Copper (I) Complexes - Ru(II) Polypyridine Complexes - Excited-State Redox Potentials - Luminescent Metal Complexes - Polypyridine Metal Complexes - Cyclometallated Complexes - Ruthenium Complexes - Rhodium Complexes - Iridium Complexes - Platinum Complexes
Hafta 10
Photochemistry and Photophysics of Metal Complexes - Photophysical Properties - Relationships between Electrochemistry and Photochemistry - Cobalt (III) Complexes - Copper (I) Complexes - Ru(II) Polypyridine Complexes - Excited-State Redox Potentials - Luminescent Metal Complexes - Polypyridine Metal Complexes - Cyclometallated Complexes - Ruthenium Complexes - Rhodium Complexes - Iridium Complexes - Platinum Complexes
Hafta 11
Photochemistry and Photophysics of Metal Complexes - Photophysical Properties - Relationships between Electrochemistry and Photochemistry - Cobalt (III) Complexes - Copper (I) Complexes - Ru(II) Polypyridine Complexes - Excited-State Redox Potentials - Luminescent Metal Complexes - Polypyridine Metal Complexes - Cyclometallated Complexes - Ruthenium Complexes - Rhodium Complexes - Iridium Complexes - Platinum Complexes
Hafta 12
Photochemistry and Photophysics of Metal Complexes - Photophysical Properties - Relationships between Electrochemistry and Photochemistry - Cobalt (III) Complexes - Copper (I) Complexes - Ru(II) Polypyridine Complexes - Excited-State Redox Potentials - Luminescent Metal Complexes - Polypyridine Metal Complexes - Cyclometallated Complexes - Ruthenium Complexes - Rhodium Complexes - Iridium Complexes - Platinum Complexes
Hafta 13
Conversion of Light into Chemical Energy - Natural Photosynthesis - Light Harvesting: Absorption and Energy Transfer - Photoinduced Electron Transfer Leading to Charge Separation - Bacterial Photosynthesis - Green Plants Photosynthesis: Photosystem II - Efficiency of Photosynthesis - Artificial Photosynthesis - Artificial Antenna - Artificial Reaction Centers - Coupling Artificial Antenna and Reaction Center - Coupling One-Photon Charge Separation with Multielectron Water Splitting - Water Splitting by Semiconductor Photocatalysis
Hafta 14
Conversion of Light into Chemical Energy - Natural Photosynthesis - Light Harvesting: Absorption and Energy Transfer - Photoinduced Electron Transfer Leading to Charge Separation - Bacterial Photosynthesis - Green Plants Photosynthesis: Photosystem II - Efficiency of Photosynthesis - Artificial Photosynthesis - Artificial Antenna - Artificial Reaction Centers - Coupling Artificial Antenna and Reaction Center - Coupling One-Photon Charge Separation with Multielectron Water Splitting - Water Splitting by Semiconductor Photocatalysis

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