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CHEM 422

Introduction to Statistical Thermodynamics

Statistical thermodynamics is where you finally see why the macroscopic laws from your earlier thermo courses actually hold: temperature, entropy, and free energy emerge from counting microstates and averaging over ensembles rather than being postulated. You'll spend the semester building partition functions for concrete systems — Einstein solids, paramagnets, ideal di- and polyatomic gases, Fermi and Bose gases, simple adsorption and polymer models — through five problem sets and two written exams, with Callen and McQuarrie as your main references. As a senior-spring requirement, it ties together classical thermo and quantum mechanics into the framework you actually need for physical chemistry research, materials, and anything involving chemical equilibrium at the molecular level.

Credit3ECTS5FacultyFaculty of ScienceBölümChemistryPreCHEM 323MüfredatY4 Bahar

Değerlendirme 100% — 4 adım

25%
25%
30%
20%
Midterm:Essay/written M1 25%
Midterm M2 25%
Final:Essay/written F 30%
Homework HW+Attendance 20%

Önerilen kaynaklar 3 kitap

📖
Önerilen
Statistical Mechanics
McQuarrie
2000 · University Science Books
📖
Önerilen
H. Callen
Thermodynamics and an Introduction to Thermostatistics
1985/2nd · Wiley
📖
Önerilen
An Introduction to Statistical Thermodynamics
T.L.Hill
1986 · Dover

Haftalık müfredat 14 hafta

Hafta 1
Review of Classical Thermodynamics:Fundamental relation, maximum entropy principle, Legendre transform, thermodynamic potentials
Hafta 2
Review of Classical Thermodynamics: Extremum principles for equilibrium, Maxwell relations, response functions, stability of thermodynamic systems
Hafta 3
Basic results of combinatorics and elementary notions of probability, information-theoretic entropy
Hafta 4
Postulates of Statistical Mechanics: Ergodic hypothesis, principle of a priori equal probabilities. Ensembles. Microcanonical ensemble
Hafta 5
Applications: Einstein model of crystals, simple model of paramagnetism, negative absolute temperature.
Hafta 6
Canonical ensemble. Calculation of canonical partition function for simple models.
Hafta 7
Grandcanonical ensemble. General ensemble theory.
Hafta 8
Fluctuations. Equivalence of ensembles
Hafta 9
Classical statistical mechanics.
Hafta 10
Systems composed of identical particles. Quantum statistics. Classical limit of quantum statistics.
Hafta 11
Classical ideal gases: mono-atomic and diatomic molecules. Nuclear-spin and statistics; ortho-para hydrogen.
Hafta 12
Vibrational and rotational partition functions for polyatomic molecules. Symmetry number.
Hafta 13
Introduction to lattice statistics: Simple models of adsorption, polymer chains.
Hafta 14
Chemical equilibrium in ideal gas mixtures

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Geçmiş GPA dağılımı 19 dönem · ort. 2.28

DönemCourse CPA
2024-2025 Spring 2.47 1 sec · 21 öğr
2023-2024 Spring 2.58 1 sec · 21 öğr
2022-2023 Spring 2.58 1 sec · 15 öğr
2021-2022 Spring 2.17 1 sec · 18 öğr
2020-2021 Spring 2.21 1 sec · 19 öğr
2019-2020 Fall 2.70 1 sec · 1 öğr
2019-2020 Spring 2.38 1 sec · 14 öğr
2018-2019 Spring 2.19 1 sec · 30 öğr
2017-2018 Spring 2.16 1 sec · 17 öğr
2016-2017 Spring 2.28 1 sec · 19 öğr

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Hocalar 1 bu dönem · 1 geçmiş

Bu dönem (2025-2026 Spring) · 1 section
Fahri Alkan
Geçmişte ders veren (1 kişi)
Zeki Cemal Kuruoğlu