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CHEM 418

Photochemistry and Photophysics

This is a course about what molecules do in the brief window after they absorb a photon — how excited states form, lose energy through radiative and radiationless pathways, transfer charge or excitation to neighbors, and occasionally drive chemistry that ground-state molecules can't. You'll work through Jablonski diagrams, selection rules, and quenching kinetics across organic chromophores and metal complexes like [Ru(bpy)3]2+, anchored by two midterms, a final, and five homeworks built on the Juris textbook. Sitting on top of physical chemistry and inorganic foundations, it's the bridge course for anyone heading toward solar energy conversion, photocatalysis, OLEDs, or the supramolecular machines that close the syllabus.

Credit3ECTS5FacultyFaculty of ScienceBölümChemistryPreCHEM 342

Değerlendirme 100% — 3 adım

50%
30%
20%
Midterm Midterm 50%
Final Final Exam 30%
Homework Homework and projects 20%

Önerilen kaynaklar 1 kitap

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Önerilen
Photochemistry and Photophysics: Concepts
Research, Applications
Paola Ceroni · Alberto Juris

Haftalık müfredat 14 hafta

Hafta 1
Introduction to Photochemistry and Photophysics
Hafta 2
Elementary Molecular Orbital Theory
Hafta 3
Light Absorption and Nature of the Excited State - Light Absorption - Selection Rules - Symmetry Selection Rules - Spin Selection Rules - The Franck–Condon Principle - Jablonski Diagram - Excited-State Deactivation - Vibrational Relaxation - Radiationless Deactivation - Radiative Deactivation - Radiative Lifetime - Chemical Reactions - Excited States: Physical and Chemical Properties: Lifetime, Energy, Geometry, Small Molecules - Selected Molecules: Oxygen, Naphthalene, Benzophenone, Zinc(II) Tetraphenyl Porphyrin, [Cr(en)3]3+, [Co(NH3)6]3+, [Ru(bpy)3]2+, Semiconductors
Hafta 4
Light Absorption and Nature of the Excited State - Light Absorption - Selection Rules - Symmetry Selection Rules - Spin Selection Rules - The Franck–Condon Principle - Jablonski Diagram - Excited-State Deactivation - Vibrational Relaxation - Radiationless Deactivation - Radiative Deactivation - Radiative Lifetime - Chemical Reactions - Excited States: Physical and Chemical Properties: Lifetime, Energy, Geometry, Small Molecules - Selected Molecules: Oxygen, Naphthalene, Benzophenone, Zinc(II) Tetraphenyl Porphyrin, [Cr(en)3]3+, [Co(NH3)6]3+, [Ru(bpy)3]2+, Semiconductors
Hafta 5
Light Absorption and Nature of the Excited State - Light Absorption - Selection Rules - Symmetry Selection Rules - Spin Selection Rules - The Franck–Condon Principle - Jablonski Diagram - Excited-State Deactivation - Vibrational Relaxation - Radiationless Deactivation - Radiative Deactivation - Radiative Lifetime - Chemical Reactions - Excited States: Physical and Chemical Properties: Lifetime, Energy, Geometry, Small Molecules - Selected Molecules: Oxygen, Naphthalene, Benzophenone, Zinc(II) Tetraphenyl Porphyrin, [Cr(en)3]3+, [Co(NH3)6]3+, [Ru(bpy)3]2+, Semiconductors
Hafta 6
Light Absorption and Nature of the Excited State - Light Absorption - Selection Rules - Symmetry Selection Rules - Spin Selection Rules - The Franck–Condon Principle - Jablonski Diagram - Excited-State Deactivation - Vibrational Relaxation - Radiationless Deactivation - Radiative Deactivation - Radiative Lifetime - Chemical Reactions - Excited States: Physical and Chemical Properties: Lifetime, Energy, Geometry, Small Molecules - Selected Molecules: Oxygen, Naphthalene, Benzophenone, Zinc(II) Tetraphenyl Porphyrin, [Cr(en)3]3+, [Co(NH3)6]3+, [Ru(bpy)3]2+, Semiconductors
Hafta 7
Molecular Organic Photochemistry - Basic Concepts - Carbonyl Compounds - Photochemistry of Other Organic Compounds - Nitrogen Compounds
Hafta 8
Molecular Organic Photochemistry - Basic Concepts - Carbonyl Compounds - Photochemistry of Other Organic Compounds - Nitrogen Compounds
Hafta 9
Photochemistry and Photophysics of Metal Complexes - Photophysical Properties - Relationships between Electrochemistry and Photochemistry - Cobalt (III) Complexes - Copper (I) Complexes - Ru(II) Polypyridine Complexes - Excited-State Redox Potentials - Luminescent Metal Complexes - Polypyridine Metal Complexes - Cyclometallated Complexes - Ruthenium Complexes - Rhodium Complexes - Iridium Complexes - Platinum Complexes
Hafta 10
Photochemistry and Photophysics of Metal Complexes - Photophysical Properties - Relationships between Electrochemistry and Photochemistry - Cobalt (III) Complexes - Copper (I) Complexes - Ru(II) Polypyridine Complexes - Excited-State Redox Potentials - Luminescent Metal Complexes - Polypyridine Metal Complexes - Cyclometallated Complexes - Ruthenium Complexes - Rhodium Complexes - Iridium Complexes - Platinum Complexes
Hafta 11
Photochemistry and Photophysics of Metal Complexes - Photophysical Properties - Relationships between Electrochemistry and Photochemistry - Cobalt (III) Complexes - Copper (I) Complexes - Ru(II) Polypyridine Complexes - Excited-State Redox Potentials - Luminescent Metal Complexes - Polypyridine Metal Complexes - Cyclometallated Complexes - Ruthenium Complexes - Rhodium Complexes - Iridium Complexes - Platinum Complexes
Hafta 12
Photochemistry and Photophysics of Metal Complexes - Photophysical Properties - Relationships between Electrochemistry and Photochemistry - Cobalt (III) Complexes - Copper (I) Complexes - Ru(II) Polypyridine Complexes - Excited-State Redox Potentials - Luminescent Metal Complexes - Polypyridine Metal Complexes - Cyclometallated Complexes - Ruthenium Complexes - Rhodium Complexes - Iridium Complexes - Platinum Complexes
Hafta 13
Conversion of Light into Chemical Energy - Natural Photosynthesis - Light Harvesting: Absorption and Energy Transfer - Photoinduced Electron Transfer Leading to Charge Separation - Bacterial Photosynthesis - Green Plants Photosynthesis: Photosystem II - Efficiency of Photosynthesis - Artificial Photosynthesis - Artificial Antenna - Artificial Reaction Centers - Coupling Artificial Antenna and Reaction Center - Coupling One-Photon Charge Separation with Multielectron Water Splitting - Water Splitting by Semiconductor Photocatalysis
Hafta 14
Conversion of Light into Chemical Energy - Natural Photosynthesis - Light Harvesting: Absorption and Energy Transfer - Photoinduced Electron Transfer Leading to Charge Separation - Bacterial Photosynthesis - Green Plants Photosynthesis: Photosystem II - Efficiency of Photosynthesis - Artificial Photosynthesis - Artificial Antenna - Artificial Reaction Centers - Coupling Artificial Antenna and Reaction Center - Coupling One-Photon Charge Separation with Multielectron Water Splitting - Water Splitting by Semiconductor Photocatalysis

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