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CHEM 418

Photochemistry and Photophysics

This is a course about what molecules do in the brief window after they absorb a photon, how excited states form, lose energy through radiative and radiationless pathways, transfer charge or excitation to neighbors, and occasionally drive chemistry that ground-state molecules can't. You'll work through Jablonski diagrams, selection rules, and quenching kinetics across organic chromophores and metal complexes like [Ru(bpy)3]2+, anchored by two midterms, a final, and five homeworks built on the Juris textbook. Sitting on top of physical chemistry and inorganic foundations, it's the bridge course for anyone heading toward solar energy conversion, photocatalysis, OLEDs, or the supramolecular machines that close the syllabus.

Kredi3ECTS5FakülteFaculty of ScienceBölümChemistryÖn koşulCHEM 342KoordinatörFerdi Karadaş

Haftalık müfredat 14 hafta

Hafta 114–20 Eyl
Photochemistry ve photophysics'e giriş
Introduction to Photochemistry and Photophysics
photochemistryphotophysics
Hafta 221–27 Eyl
Temel molecular orbital theory
Elementary Molecular Orbital Theory
molecular orbital theory
Hafta 328 Eyl – 4 Eki
Işık soğurulması ve excited state özellikleri
Light Absorption and Nature of the Excited State - Light Absorption - Selection Rules - Symmetry Selection Rules - Spin Selection Rules - The Franck-Condon Principle - Jablonski Diagram - Excited-State Deactivation - Vibrational Relaxation - Radiationless Deactivation - Radiative Deactivation - Radiative Lifetime - Chemical Reactions - Excited States: Physical and Chemical Properties: Lifetime, Energy, Geometry, Small Molecules - Selected Molecules: Oxygen, Naphthalene, Benzophenone, Zinc(II) Tetraphenyl Porphyrin, [Cr(en)3]3+, [Co(NH3)6]3+, [Ru(bpy)3]2+, Semiconductors
selection rules (symmetry, spin)Franck-Condon principleJablonski diagramexcited-state deactivation
Hafta 45–11 Eki
Işık soğurulması ve excited state özellikleri
Light Absorption and Nature of the Excited State - Light Absorption - Selection Rules - Symmetry Selection Rules - Spin Selection Rules - The Franck-Condon Principle - Jablonski Diagram - Excited-State Deactivation - Vibrational Relaxation - Radiationless Deactivation - Radiative Deactivation - Radiative Lifetime - Chemical Reactions - Excited States: Physical and Chemical Properties: Lifetime, Energy, Geometry, Small Molecules - Selected Molecules: Oxygen, Naphthalene, Benzophenone, Zinc(II) Tetraphenyl Porphyrin, [Cr(en)3]3+, [Co(NH3)6]3+, [Ru(bpy)3]2+, Semiconductors
selection rules (symmetry, spin)Franck-Condon principleJablonski diagramexcited-state deactivation
Hafta 512–18 Eki
Işık soğurulması ve excited state özellikleri
Light Absorption and Nature of the Excited State - Light Absorption - Selection Rules - Symmetry Selection Rules - Spin Selection Rules - The Franck-Condon Principle - Jablonski Diagram - Excited-State Deactivation - Vibrational Relaxation - Radiationless Deactivation - Radiative Deactivation - Radiative Lifetime - Chemical Reactions - Excited States: Physical and Chemical Properties: Lifetime, Energy, Geometry, Small Molecules - Selected Molecules: Oxygen, Naphthalene, Benzophenone, Zinc(II) Tetraphenyl Porphyrin, [Cr(en)3]3+, [Co(NH3)6]3+, [Ru(bpy)3]2+, Semiconductors
selection rules (symmetry, spin)Franck-Condon principleJablonski diagramexcited-state deactivation
Hafta 619–25 Eki
Işık soğurulması ve excited state özellikleri
Light Absorption and Nature of the Excited State - Light Absorption - Selection Rules - Symmetry Selection Rules - Spin Selection Rules - The Franck-Condon Principle - Jablonski Diagram - Excited-State Deactivation - Vibrational Relaxation - Radiationless Deactivation - Radiative Deactivation - Radiative Lifetime - Chemical Reactions - Excited States: Physical and Chemical Properties: Lifetime, Energy, Geometry, Small Molecules - Selected Molecules: Oxygen, Naphthalene, Benzophenone, Zinc(II) Tetraphenyl Porphyrin, [Cr(en)3]3+, [Co(NH3)6]3+, [Ru(bpy)3]2+, Semiconductors
selection rules (symmetry, spin)Franck-Condon principleJablonski diagramexcited-state deactivation
Hafta 726 Eki – 1 Kas
Moleküler organik photochemistry: temel kavramlar
Molecular Organic Photochemistry - Basic Concepts - Carbonyl Compounds - Photochemistry of Other Organic Compounds - Nitrogen Compounds
organic photochemistrycarbonyl compoundsnitrogen compoundsorganik bileşiklerin fotokimyası
Hafta 82–8 Kas
Moleküler organik photochemistry: temel kavramlar
Molecular Organic Photochemistry - Basic Concepts - Carbonyl Compounds - Photochemistry of Other Organic Compounds - Nitrogen Compounds
organic photochemistrycarbonyl compoundsnitrogen compoundsorganik bileşiklerin fotokimyası
Hafta 99–15 Kas
Metal Komplekslerinin Photochemistry ve Photophysics'i
Photochemistry and Photophysics of Metal Complexes - Photophysical Properties - Relationships between Electrochemistry and Photochemistry - Cobalt (III) Complexes - Copper (I) Complexes - Ru(II) Polypyridine Complexes - Excited-State Redox Potentials - Luminescent Metal Complexes - Polypyridine Metal Complexes - Cyclometallated Complexes - Ruthenium Complexes - Rhodium Complexes - Iridium Complexes - Platinum Complexes
photophysical propertiesexcited-state redox potentialsRu(II) polypyridine complexescyclometallated complexes
Hafta 1016–22 Kas
Metal Komplekslerinin Photochemistry ve Photophysics'i
Photochemistry and Photophysics of Metal Complexes - Photophysical Properties - Relationships between Electrochemistry and Photochemistry - Cobalt (III) Complexes - Copper (I) Complexes - Ru(II) Polypyridine Complexes - Excited-State Redox Potentials - Luminescent Metal Complexes - Polypyridine Metal Complexes - Cyclometallated Complexes - Ruthenium Complexes - Rhodium Complexes - Iridium Complexes - Platinum Complexes
photophysical propertiesexcited-state redox potentialsRu(II) polypyridine complexescyclometallated complexes
Hafta 1123–29 Kas
Metal Komplekslerinin Photochemistry ve Photophysics'i
Photochemistry and Photophysics of Metal Complexes - Photophysical Properties - Relationships between Electrochemistry and Photochemistry - Cobalt (III) Complexes - Copper (I) Complexes - Ru(II) Polypyridine Complexes - Excited-State Redox Potentials - Luminescent Metal Complexes - Polypyridine Metal Complexes - Cyclometallated Complexes - Ruthenium Complexes - Rhodium Complexes - Iridium Complexes - Platinum Complexes
photophysical propertiesexcited-state redox potentialsRu(II) polypyridine complexescyclometallated complexes
Hafta 1230 Kas – 6 Ara
Metal Komplekslerinin Photochemistry ve Photophysics'i
Photochemistry and Photophysics of Metal Complexes - Photophysical Properties - Relationships between Electrochemistry and Photochemistry - Cobalt (III) Complexes - Copper (I) Complexes - Ru(II) Polypyridine Complexes - Excited-State Redox Potentials - Luminescent Metal Complexes - Polypyridine Metal Complexes - Cyclometallated Complexes - Ruthenium Complexes - Rhodium Complexes - Iridium Complexes - Platinum Complexes
photophysical propertiesexcited-state redox potentialsRu(II) polypyridine complexescyclometallated complexes
Hafta 137–13 Ara
Doğal ve yapay photosynthesis, water splitting
Conversion of Light into Chemical Energy - Natural Photosynthesis - Light Harvesting: Absorption and Energy Transfer - Photoinduced Electron Transfer Leading to Charge Separation - Bacterial Photosynthesis - Green Plants Photosynthesis: Photosystem II - Efficiency of Photosynthesis - Artificial Photosynthesis - Artificial Antenna - Artificial Reaction Centers - Coupling Artificial Antenna and Reaction Center - Coupling One-Photon Charge Separation with Multielectron Water Splitting - Water Splitting by Semiconductor Photocatalysis
photosynthesischarge separationPhotosystem IIwater splitting
Hafta 1414–20 Ara
Doğal ve yapay photosynthesis, water splitting
Conversion of Light into Chemical Energy - Natural Photosynthesis - Light Harvesting: Absorption and Energy Transfer - Photoinduced Electron Transfer Leading to Charge Separation - Bacterial Photosynthesis - Green Plants Photosynthesis: Photosystem II - Efficiency of Photosynthesis - Artificial Photosynthesis - Artificial Antenna - Artificial Reaction Centers - Coupling Artificial Antenna and Reaction Center - Coupling One-Photon Charge Separation with Multielectron Water Splitting - Water Splitting by Semiconductor Photocatalysis
photosynthesischarge separationPhotosystem IIwater splitting

Değerlendirme 100% · 3 adım

50%
30%
20%
Midterm Midterm 50%
Final Final Exam 30%
Homework Homework and projects 20%
en büyük tek kalem %50 · sınav ağırlığı %80 nasıl hesaplanıyor

Önerilen kaynaklar 1 kitap

📖
Önerilen
Photochemistry and Photophysics: Concepts
Research, Applications
Paola Ceroni · Alberto Juris

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